Parthenium hysterophorus, an invasive weed, is rapidly spreading across tropical and subtropical regions, causing significant ecological and health issues. Despite its negative impact, recent research highlights its potential as a sustainable, low-cost lignocellulosic material for polymer composites. This paper explores the chemical composition, physical properties, and processing techniques of parthenium, focusing on its use as a reinforcement in thermoset and thermoplastic matrices. Parthenium biomass is primarily composed of cellulose, hemicellulose, and lignin, which make it suitable for composite applications. Surface treatments, such as alkali treatment, enhance the bonding between parthenium fibers and polymer matrices, improving mechanical interlocking. The resulting composites show enhanced mechanical properties, including increased tensile strength and flexural stiffness, with potential applications in automotive and engineering sectors. Additionally, parthenium-derived lignin has been explored for use in nanocomposites, offering UV-blocking and antioxidant properties. The paper discusses the environmental benefits of utilizing parthenium, such as reduced reliance on synthetic fibers, and highlights the challenges in ensuring consistent fiber quality and moisture sensitivity. Future research should focus on standardizing fiber extraction methods and developing hybrid composites to further enhance the performance of parthenium-based materials. In conclusion, parthenium presents a promising, eco-friendly alternative for polymer composites, contributing to the development of sustainable and biodegradable materials.
Introduction
Parthenium hysterophorus, commonly known as Congress grass or fool’s weed, is a highly invasive species that threatens biodiversity, agriculture, and public health, especially in tropical and subtropical regions like India. It reduces crop yields, degrades soil quality, and causes allergic reactions such as asthma and dermatitis.
Despite its harmful ecological impact, recent research highlights its potential as a low-cost, sustainable reinforcement material in polymer composites due to its lignocellulosic composition (cellulose, hemicellulose, and lignin).
Chemical Composition and Suitability
Parthenium biomass contains:
~78% holocellulose (cellulose + hemicellulose)
~17% lignin
Secondary metabolites (e.g., parthenin), which can be removed during processing
Cellulose provides strength and stiffness, hemicellulose enhances flexibility and bonding, and lignin contributes rigidity and thermal stability. Alkali treatment improves fiber–matrix adhesion by removing surface impurities.
Physical Characteristics
Low density → suitable for lightweight composites
Roughened surface (after chemical treatment) → better mechanical interlocking
Surface treatments are required to improve dimensional stability and durability.
Processing and Fabrication
Parthenium fibers are incorporated into:
Thermoset composites (Epoxy): Improved tensile strength and modulus using hand lay-up and compression molding.
Thermoplastic composites (PLA, ABS): Enhanced tensile and flexural properties, including 3D printing applications.
Lignin-based nanocomposites: Parthenium lignin used in ZnO nanocomposites for UV-blocking and weather resistance.
Preprocessing steps include drying, alkali treatment (NaOH), washing, and oven drying to ensure fiber quality.
Mechanical Performance
1. Epoxy-Based Composites
Increased tensile strength and stiffness at optimal fiber loading
Improved flexural and impact properties
Excess fiber content may reduce performance due to agglomeration
2. Thermoplastic Composites (PLA, ABS)
Enhanced strength and load-bearing capacity
Fiber alignment in 3D printing significantly affects performance
3. Lignin-Based Nanocomposites
Improved UV resistance and weathering performance
Potential multifunctional additive properties
Structure–Property Relationships
Mechanical performance depends on:
Cellulose content and fiber orientation
Interfacial bonding between fiber and matrix
Surface treatment (e.g., NaOH) for improved adhesion
Effective stress transfer between fiber and polymer matrix is critical.
Environmental and Economic Benefits
Converts invasive weed into valuable material
Reduces environmental damage and seed spread
Low-cost, renewable, and biodegradable resource
Decreases reliance on synthetic fibers (glass/carbon)
Supports sustainable composite production
Challenges and Future Prospects
Key limitations include:
Variability in fiber quality (location, season, plant part)
Moisture sensitivity
Limited thermal stability compared to synthetic fibers
Future research should focus on:
Standardized extraction and treatment methods
Hybrid composites with natural/synthetic fibers
Compatibilizer development
Life-cycle sustainability assessment
Conclusion
In conclusion, parthenium hysterophorus holds significant potential as a low-cost, sustainable reinforcement material for polymer composites. Despite the challenges, such as variability in fiber quality and moisture sensitivity, its abundant availability and eco-friendly characteristics make it a viable alternative to traditional synthetic fibers. With continued research and development, parthenium-based composites could play a vital role in creating lightweight, high-performance, and environmentally responsible materials for a wide range of industrial applications.
References
[1] Behera, S., Arora, R., Nandhagopal, N., & Kumar, S. (2014). Importance of chemical pretreatment for bioconversion of lignocellulosic biomass. Renewable and Sustainable Energy Reviews, 36, 91–106.
[2] Biswas, M. (2025). Physico-chemical properties of natural fibers from invasive alien plants with potential for biocomposite applications. Journal of Plant Science Research, 41(3), 245–258.
[3] Dey, P., Samanta, R., Saha, P., & Roy, P. K. (2011). Effect of alkali treatment on physicochemical and mechanical properties of Parthenium hysterophorus fiber. Cellulose Chemistry and Technology, 45(7–8), 487–494.
[4] Gopinath, A., Kumar, M. S., & Elayaperumal, A. (2015). Mechanical properties and SEM analysis of Parthenium hysterophorus short fiber reinforced epoxy composites. International Journal of Engineering and Technology, 7(3), 172–178.
[5] Gopinath, A., Senthil Kumar, M., & Elayaperumal, A. (2014). Experimental investigations on mechanical properties of Parthenium hysterophorus fiber reinforced polymer composites. International Journal of Advanced Engineering Technology, 5(2), 95–99.
[6] Khan, H., Jawaid, M., & Khan, A. N. (2020). A review on 3D printed polymer composites reinforced with natural fibers. Journal of Materials Research and Technology, 9(6), 13749–13768.
[7] Kumar, P. S., Arumugam, V., & Manikandan, V. (2019). Experimental studies on mechanical properties and characterization of Parthenium short fibre reinforced polymer matrix composites. International Journal of Engineering and Advanced Technology, 8(2S), 95–100.
[8] Lian, M., Sharma, A., & Gupta, R. (2024). Utilization of Parthenium hysterophorus for the synthesis of lignin–ZnO nanocomposites aimed at boosting UV shielding and stability. Letters in Applied NanoBioScience, 13(4), 171–183.
[9] Mohammed, L., Ansari, M. N. M., Pua, G., Jawaid, M., & Islam, M. S. (2015). A review on natural fiber reinforced polymer composite and its applications. International Journal of Polymer Science, 2015, 1–15.
[10] Nirmal, U., Hashim, J., & Aqiql, M. (2017). A review on tribological performance of natural fiber reinforced polymer composite. Tribology International, 109, 437–449.
[11] Patel, S. (2013). Harmful and beneficial aspects of Parthenium hysterophorus: An update. 3 Biotech, 3(5), 425–436.
[12] Prasanna, B. M., & Reddy, G. V. (2012). Lignocellulosic characterization of Parthenium hysterophorus as a potential raw material for composite applications. International Journal of Polymer Science, 2012, 1–7.
[13] Ramesh, M. (2016). Kenaf (Hibiscus cannabinus L.) fiberbased bio materials: A review on processing and properties. Progress in Materials Science, 78–79, 1–92.
[14] Reddy, N., & Yang, Y. (2014). Biofibers from invasive plants and their applications in biocomposites. Industrial Crops and Products, 52, 560–568.
[15] Saini, G., & Sirohi, R. (2018). Valorization of Parthenium hysterophorus biomass for biobased materials: Opportunities and challenges. Bioresource Technology Reports, 3, 142–149.
[16] Sanchita, G., Tiwari, R., & Raghuwanshi, S. (2017). Cost-effective cellulase production using Parthenium hysterophorus biomass as substrate. AMB Express, 7, 1–12.
[17] Sathishkumar, T., Navaneethakrishnan, P., Shankar, S., Rajasekar, R., & Rajini, N. (2014). Characterization of natural fibers and composites A review. Journal of Reinforced Plastics and Composites, 33(13), 1258–1275.
[18] Sharma, A., Singh, P., & Verma, P. (2020). Ultrasound-assisted alkaline pretreatment of Parthenium hysterophorus for enhanced delignification and cellulose enrichment. Bioresource Technology Reports, 11, 100477.
[19] Singh, S., & Singh, A. (2015). Chemical composition and structural analysis of Parthenium hysterophorus biomass for material applications. Journal of Natural Fibers, 12(5), 452–463.
[20] Vijay, K., Pujari, S., & Rao, G. (2023). Effect of alkali treatment on cellulose content and mechanical behavior of Parthenium hysterophorus fiber for polymer composites. Journal of Natural Fibers, 20(7), 1234–1248.